He arrived there on Monday (4 April) following the departure from the Nottingham site of the previous incumbent, Gary Evans.
Caley, a former Polestar group commercial director who left the company in January 2004, said that he was unaware of the circumstances behind Evans' departure.
He said: "I'm really excited about this. I like the challenge, and Polestar Chromoworks is a good company with an exciting customer list."
Caley has been working in a similar consulting role at Polestar Purnell for the past few months. He said that the period of his contract at Chromoworks was "as long as a piece of string".
Neither Gary Evans nor Chromoworks site director Peter Greaves were available for comment.
Story by Josh Brooks
Chromoworks role for Caley
Print consultant Bob Caley has joined Polestar Chromoworks to cover the role of sales and commercial director.