Catherine Hearn joins the group on 1 July and replaces Geof Garwood, who retired last September.
She joined Guinness Brewing in June 1996 as employee relations and policy director, before becoming human resources director for some of the Guinness international markets.
Following the integration of Guinness Brewing and UDV, Hearn became human resources director of Diageo Business Services, where she has driven a redesign of business processes and established a new business services centre in Budapest.
Her career also includes seven years at London Transport.
Polestar chief executive Barry Hibbert said Hearn was clearly the calibre of person we were looking for.
Have your say in the Printweek Poll
Related stories
Latest comments
"And here's me thinking they bought the Docklands Light Railway."
"15 x members? Why don't they throw their lot in with the Strategic Mailing Partnership (SMP) and get a louder voice?"
"Some forty plus years ago I was at a "sales" training seminar and got chatting to the trainer after the session had finished.
In that conversation he told me about another seminar he had..."
Up next...

Customer demand increasing
A4 Laser Labels expands with larger site and kit investment

Price rises in US 'to at least partially offset' costs
Cimpress withdraws guidance due to Trump's tariffs

Proceeds to be invested in growth strategy
James Cropper sells some specialist IP

Making changes to limit tariff impact in US